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MAC address filtering is nota security measure, it is more an administrative measure. You can spoof a MAC address easily.If however the WiFi network, and from your clarification I gather it is about a WiFi network, has a WPA2 based passhphrase, there is no point in spoofing the MAC address as access to the network would be difficult. I have a Quicksilver 2002 800mhz on 10.2.2 and I have never been able to use the 'wake for Administrative access' function through ssh, eihter from a windowz machine or a Mac over the network.
You don't become a hacker overnight. I'm 5 years in, and still learning new things everyday. It takes years of studying, trial and error, and sheer determination. Best bet is to pick up a book on ruby or python and start from there. And learn the terminology, because putting 'how to hack' in google will just about get you no where. Also, join a forum, and don't ask people dumb shit, like 'how do you hack facebook?' , cause you'll get harrased and you'll piss people off!
And, have a lot of determination, and paitince, cause you'll need it!